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"Energy" of the three main themes in today s world, "green", "quality" has been a high degree of attention of Governments, China has also introduced various policies around these themes, is to take various measures to promote sustainable urban and rural construction developments.
New plastic pipe fittings applied to the northern winter heating system, the epoch-making revolution has been accepted, and its energy-saving and environmental protection is the fundamental basis of its vitality, so the introduction of a few short decades, especially in the last five years, its rapid development trend is in the ascendant, the varieties of the pipe from the PB and plastic composite pipe, PP-C (B), PP-R, developed to the now widespread use of PE-Xa, PE-Xb, PE -Xc, PE-RT, brass, especially the application of PE-Xa pipe is more prominent, according to incomplete statistics, the reservation will reach 70% of the amount of warm pipe, for, the pros and cons of the pipe quality will directly affect the to warm the sound development of the industry insiders are concerned about this problem, the pipe manufacturer, however, there are several carefully quality issues rose to the height of morality to treat it today, Tangshan Road – the management company is willing to PE-Xa pipe, several quality control of key technologies to introduce to you and hope that help the industry and give each to warm ".
The quality control of PE-Xa pipestainless steel pipe fittings
Really achieve more than 50 years in order to ensure that the pipe quality, the service life of the pipe, in order to better promote the development of the industry to warm, as the pipe production enterprises should strictly control the quality of a good pipe.
The author with the experience of six years, the production of PE-X pipe PE-Xa pipe production and quality control points are the following several:
The choice of a base material
Excellent performance, stable quality raw material for producing high-quality PE-Xa pipe, China s production of PE-Xa pipe s Special Compound is totally dependent on imports from South Korea, South Korea, the production of special materials manufacturer LG Chem, Hunan ( HONAM) Petrochemical, Samsung integrated chemical and Korean oil such as several large petrochemical enterprises. If large-scale production, the author recommends that the manufacturers choose LG Chem XL1800 and Honam Petrochemical s 8100GX two grades of high density polyethylene powder as a PE-Xa pipe base material. LG Chem, the first PE-Xa pipes and PE-Xa Pipe Compound XL1800 introduced from Korea to China, paid a lot of effort for PE-Xa pipes and floor heating in China to promote the development of our floor heating industry has made tremendous contribution to LG Chemical s PE-Xa Pipe Compound production and sales volume ranked first with a fairly stable product quality, delivery is guaranteed, and its after-sales service system is very well suited for mass production. Honam Petrochemical is the first Asian production of PE-Xa Pipe Compound enterprises, production is also produced within the pipe quality and appearance quality are excellent, but due to sales of Honam Petrochemical the 8100GX this special materials rely on a Korean agency (South Korean the BCF trading company), after-sales service compared to LG Chem, is slightly inferior, and marketing efforts. Private industry materials for these two manufacturers have factories both in the author s high-volume applications, all through the thermal stability test more than 10,000 hours. Several other manufacturers in South Korea is smaller due to the production of such special materials, little promotion efforts in China, often in the domestic stock, so I do not recommend large-scale manufacturers choose.
In addition, I learned that the Southern small workshop-style factory production of PE-Xa pipe, special base compound by adding the common low molecular weight of ordinary polyethylene powder in order to reduce costs, this approach is very desirable to produce pipe performance will be greatly reduced and will eventually affect the entire industry, in order to warm the healthy development of the industry in China, I called the manufacturers and users and some of the functions of departments to monitor such behavior.
Selection and formulation of excipients
PE-Xa pipe formulations were less, and non-polluting non-toxic additives, PE-Xa pipe production used the following several additives:
(A) cross-linking agent
Di-tert-butyl peroxide DTBP formula C8H18O2
(2) the main antioxidant
Recommended Use: antioxidant 1076 (octadecadienoic propionate ester) Molecular formula C35H62O3
Antioxidant 1076 phenolic antioxidants, is an excellent non-polluting non-toxic antioxidant. Good compatibility with resin, high antioxidant properties, resistance to washing, volatile small, widely used in polyethylene, polypropylene, polystyrene, ABS, PVC, polyester and other plastic products, the biggest feature is the anti- the melting point of the oxygen dose is relatively low, more compatible with the plunger-type extruder such extrusion process without mixing function. Individual Korea s raw materials provided by the manufacturer, the main antioxidant in the recipe selected antioxidant 1010, but after I test the antioxidant 1010 due to the melting point is too high, in the Engel method processes the application can not be fully molten, not only will not achieve antioxidant effect of the application, but also in the PE-Xa pipe wall to form a small antioxidant crystalline block, so that the pressure resistance of pipe affected my humble opinion, antioxidant 1010 is not suitable for Engel of PE- Xa pipe.
(3) secondary antioxidants
Recommend the use of antioxidants DSTDP
The antioxidant DSTDP belong to the auxiliary antioxidant and phenolic antioxidants (antioxidants 1010,1076, etc.) and a synergistic effect can greatly enhance the antioxidant effect of phenolic antioxidants
According to data provided by South Korea s Honam Petrochemical Research Institute, a separate antioxidant 1076, rather than using assisted the antioxidant DSTDP production tubing, and its thermal stability test (110 ° C, the ring of the results of the stress 2.5Mpa) only up to 7000 hours the same specifications as the same wall thickness of pipe, using the combination of antioxidant formula, the thermal stability test results all the more than 8760 hours, I factory pipe using a combination of antioxidant formulations, and in accordance with South Korea s LG formula appropriate adjustments in the National Chemical Building Materials Test Center through 11,500 hours of thermal stability test, in normal operating conditions, the service life of up to 65 years. To remind the user of each PE-Xa pipe respective manufacturers in order to reduce costs and improve the appearance quality of the pipe, do not use these two antioxidants, long-term performance of this pipe does not have any guarantee that the method of figuring : added antioxidants pipe look slightly yellow, transparency will reduce, not add antioxidants pipe color plainer higher degree of transparency, so that the PE-Xa pipe should not be too fancy pipe appearance plainer. transparent, this pipe is likely not added antioxidant products.sanitary pipe fittings
3 control of the mixing process of raw materials
(1) PE-Xa pipe production using a special piston extruder, this production process the raw material mixing features, and accessories in the cross-linking agent and antioxidant in HDPE are distributed evenly a direct impact on the performance of the pipe, This is controlled by the mixing process, in order to ensure the stable quality of the pipe, the mixing process, the following tasks:
(2) mixing time :12-15 minutes
(3) mixer speed :250-350rpm, if conditions allow, it is recommended to use a two-speed mixer accessories in the high-speed mixing, mixing for 3-5 minutes, replaced by low-speed mixing.
(4) mixing temperature: a good mix raw material temperature should be between 30-35 ℃, the temperature is too low, is not conducive to the dispersion of the crosslinking agent in the HDPE powder, resulting in uneven pipe cross-linking, the temperature is too high will so that the crosslinker volatile, resulting in the pipe cross-linking is too low, the thermal strength of the pipe to reduce, and ultimately shorten the life of the pipe. In order to ensure a proper mixing temperature, it is recommended to use the mixer with a water-cooled devices.
Process temperature control
(1) to set the policy – of the process temperature in the pipe does not affect the degree of crosslinking and the appearance quality of the premise, the temperature set as low as possible.
(2) the temperature of the mold the front of the feed zone (body, adapter above) can not be too high, the maximum should not exceed 180 ° C, otherwise it will appear the phenomenon of pre-crosslinked and crosslinked materials in advance will cover the inner wall of the adapter and shunt at the cone, over time will cause carbonization off, together with the pipe extrusion, in the formation of impurities within the wall, and can easily leak in the construction of suppressing and the process of using, and recommended that each PE-Xa pipe production enterprises regularly clean up the squeeze the machine adapter and shunt cone.
(3) The raw materials of the formula is fixed, the production process temperature in accordance with changes in pipe production speed and make the appropriate adjustments, the only way to ensure the pipe cross-linked stable.
Production rate and degree of crosslinking of control
(1) In order to ensure the long-term performance of PE-Xa pipe, taking into account the manufacturer s production efficiency, it is recommended that the production rate should be controlled at 1.2-1.6 m / min.
(2) the degree of crosslinking of PE-Xa pipe is not as high as possible, the reason for the degree of crosslinking of PE-Xa pipe is higher than the degree of crosslinking of PE-Xb pipe, to eliminate both because of cross-linked structure different impact on performance differences, but the cross-linking through the high will affect the pressure resistance of the pipe, from personal experience, degree of crosslinking should be controlled within 80% -85% range.
(3) The following is the Tao Cheng a group of test data, for information:
(4) In order to ensure the long-term performance of PE-Xa pipe, taking into account the manufacturer s production efficiency, it is recommended that the production rate should be controlled at 1.2-1.6 m / min.
(5) the degree of crosslinking of PE-Xa pipe is not as high as possible, the reason for the degree of crosslinking of PE-Xa pipe is higher than the degree of crosslinking of PE-Xb pipe, to eliminate both because of cross-linked structure different impact on performance differences, but the cross-linking through the high will affect the pressure resistance of the pipe, from personal experience, degree of crosslinking should be controlled within 80% -85% range.
(6) The following is the Tao Cheng a group of test data, for information:
The degree of crosslinking
Production rate
At room temperature blasting pressure
Sample a
85%
1.4m/min
4.5Mpa
Sample two
85%
1.8m/min
4.0Mpasanitary fittings
Sample three
80%
1.5m/min
4.4Mpa
Sample four
95%
1.5m/min
3.8Mpa
6. Pipe factory inspection
Factory inspection of the pipe should be strictly carried out in accordance with the the GB/T18992.2-2003 standards requirements of the project inspection, for each test them here in this standard does not mention the thickness deviation rate, I suggest that each production companies may refer to the industry standard CJ/T205-2000 requirements, wall thickness deviation of not more than 14%